<?xml version="1.0" encoding="UTF-8" ?>
<PDBx:datablock  datablockName="3HYA" 
            xmlns:PDBx="http://deposit.pdb.org/pdbML/pdbx.xsd"
            xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
            xsi:schemaLocation="http://deposit.pdb.org/pdbML/pdbx.xsd pdbx.xsd">
   <PDBx:audit_authorCategory>
      <PDBx:audit_author name="Arnott, S."></PDBx:audit_author>
   </PDBx:audit_authorCategory>
   <PDBx:cellCategory>
      <PDBx:cell entry_id="3HYA">
         <PDBx:length_a>11.530</PDBx:length_a>
         <PDBx:length_b>9.890</PDBx:length_b>
         <PDBx:length_c>33.860</PDBx:length_c>
         <PDBx:angle_alpha>90.00</PDBx:angle_alpha>
         <PDBx:angle_beta>90.00</PDBx:angle_beta>
         <PDBx:angle_gamma>90.00</PDBx:angle_gamma>
         <PDBx:Z_PDB>8</PDBx:Z_PDB>
      </PDBx:cell>
   </PDBx:cellCategory>
   <PDBx:database_PDB_matrixCategory>
      <PDBx:database_PDB_matrix entry_id="3HYA">
         <PDBx:origx11>.100000</PDBx:origx11>
         <PDBx:origx12>0.000000</PDBx:origx12>
         <PDBx:origx13>0.000000</PDBx:origx13>
         <PDBx:origx21>0.000000</PDBx:origx21>
         <PDBx:origx22>.100000</PDBx:origx22>
         <PDBx:origx23>0.000000</PDBx:origx23>
         <PDBx:origx31>0.000000</PDBx:origx31>
         <PDBx:origx32>0.000000</PDBx:origx32>
         <PDBx:origx33>.100000</PDBx:origx33>
         <PDBx:origx_vector1>0.00000</PDBx:origx_vector1>
         <PDBx:origx_vector2>0.00000</PDBx:origx_vector2>
         <PDBx:origx_vector3>0.00000</PDBx:origx_vector3>
      </PDBx:database_PDB_matrix>
   </PDBx:database_PDB_matrixCategory>
   <PDBx:database_PDB_remarkCategory>
      <PDBx:database_PDB_remark id="2">
         <PDBx:text>
RESOLUTION. 3.0 ANGSTROMS.</PDBx:text>
      </PDBx:database_PDB_remark>
      <PDBx:database_PDB_remark id="3">
         <PDBx:text>
REFINEMENT. BY A LINKED-ATOM LEAST-SQUARES MODEL-BUILDING
 PROCEDURE.  SEE REFERENCE 1 ABOVE.</PDBx:text>
      </PDBx:database_PDB_remark>
      <PDBx:database_PDB_remark id="4">
         <PDBx:text>
THE CRYSTALLOGRAPHIC ASYMMETRIC UNIT OF THIS STRUCTURE
COMPRISES TWO GCU-NAG PAIRS OF RESIDUES.  IN ORDER TO ALLOW
FACILE GENERATION OF THE LONG CHAIN WHICH REALISTICALLY
REPRESENTS THE STRUCTURE, COORDINATES FOR THE CHAIN SEGMENT
LIMITED BY THE UNIT-CELL REPEAT DISTANCE IN THE Z DIRECTION
ARE GIVEN HERE.  BY REPEATED TRANSLATION OF 33.86 ANGSTROMS
IN THE Z DIRECTION THE FULL STRUCTURE OF THE POLYMER MAY BE
OBTAINED.</PDBx:text>
      </PDBx:database_PDB_remark>
      <PDBx:database_PDB_remark id="5">
         <PDBx:text>
THE EIGHT-RESIDUE CHAIN SEGMENT GIVEN HERE WAS GENERATED
FROM THE PUBLISHED FOUR-RESIDUE SEGMENT BY APPLICATION OF
THE 21 SCREW AXIS AS DEFINED IN THE FOOTNOTE TO TABLE 8 OF
THE PAPER CITED IN THE JRNL RECORDS ABOVE.</PDBx:text>
      </PDBx:database_PDB_remark>
      <PDBx:database_PDB_remark id="6">
         <PDBx:text>
THE SPACE GROUP USED FOR THIS ANALYSIS WAS P 21 21 21 IN A
NON STANDARD SETTING WITH THE 21 AXIS PARALLEL TO Z PASSING
THROUGH X=0,Y=0 AND THE 21 AXIS PARALLEL TO X IN THE Z=0
PLANE.</PDBx:text>
      </PDBx:database_PDB_remark>
      <PDBx:database_PDB_remark id="7">
         <PDBx:text>
CORRECTION. CHANGE ISSN CODE FOR REFERENCE 1.  01-OCT-80.</PDBx:text>
      </PDBx:database_PDB_remark>
      <PDBx:database_PDB_remark id="8">
         <PDBx:text>
CORRECTION. INSERT REVDAT RECORDS. 30-SEP-83.</PDBx:text>
      </PDBx:database_PDB_remark>
      <PDBx:database_PDB_remark id="9">
         <PDBx:text>
CORRECTION. INSERT MISSING * IN FORMUL RECORD FOR HOH.
 STANDARDIZE ATOM NAMING FOR NAG BY CHANGING N TO N2.
 15-JUL-92.</PDBx:text>
      </PDBx:database_PDB_remark>
   </PDBx:database_PDB_remarkCategory>
   <PDBx:database_PDB_revCategory>
      <PDBx:database_PDB_rev num="1">
         <PDBx:date>1980-03-28</PDBx:date>
         <PDBx:date_original>1977-11-20</PDBx:date_original>
         <PDBx:replaces>3HYA</PDBx:replaces>
         <PDBx:mod_type>0</PDBx:mod_type>
      </PDBx:database_PDB_rev>
      <PDBx:database_PDB_rev num="2">
         <PDBx:date>1980-10-01</PDBx:date>
         <PDBx:replaces>3HYA</PDBx:replaces>
         <PDBx:mod_type>1</PDBx:mod_type>
      </PDBx:database_PDB_rev>
      <PDBx:database_PDB_rev num="3">
         <PDBx:date>1983-09-30</PDBx:date>
         <PDBx:replaces>3HYA</PDBx:replaces>
         <PDBx:mod_type>1</PDBx:mod_type>
      </PDBx:database_PDB_rev>
      <PDBx:database_PDB_rev num="4">
         <PDBx:date>1992-07-15</PDBx:date>
         <PDBx:replaces>3HYA</PDBx:replaces>
         <PDBx:mod_type>3</PDBx:mod_type>
      </PDBx:database_PDB_rev>
      <PDBx:database_PDB_rev num="5">
         <PDBx:date>2003-04-01</PDBx:date>
         <PDBx:replaces>3HYA</PDBx:replaces>
         <PDBx:mod_type>1</PDBx:mod_type>
      </PDBx:database_PDB_rev>
   </PDBx:database_PDB_revCategory>
   <PDBx:database_PDB_tvectCategory>
      <PDBx:database_PDB_tvect id="1">
         <PDBx:vector1>0.00000</PDBx:vector1>
         <PDBx:vector2>0.00000</PDBx:vector2>
         <PDBx:vector3>33.86000</PDBx:vector3>
      </PDBx:database_PDB_tvect>
   </PDBx:database_PDB_tvectCategory>
   <PDBx:exptlCategory>
      <PDBx:exptl entry_id="3HYA">
         <PDBx:method>X-RAY DIFFRACTION</PDBx:method>
      </PDBx:exptl>
   </PDBx:exptlCategory>
   <PDBx:refineCategory>
      <PDBx:refine entry_id="3HYA">
         <PDBx:ls_d_res_low xsi:nil="true" />
         <PDBx:ls_d_res_high>3.0</PDBx:ls_d_res_high>
      </PDBx:refine>
   </PDBx:refineCategory>
   <PDBx:struct_keywordsCategory>
      <PDBx:struct_keywords entry_id="3HYA">
         <PDBx:pdbx_keywords>TEXTURE OF CONNECTIVE TISSUE</PDBx:pdbx_keywords>
         <PDBx:text>TEXTURE OF CONNECTIVE TISSUE</PDBx:text>
      </PDBx:struct_keywords>
   </PDBx:struct_keywordsCategory>
   <PDBx:symmetryCategory>
      <PDBx:symmetry entry_id="3HYA">
         <PDBx:space_group_name_H-M>P 21 21 21</PDBx:space_group_name_H-M>
      </PDBx:symmetry>
   </PDBx:symmetryCategory>
   <PDBx:entryCategory>
      <PDBx:entry id="3HYA"></PDBx:entry>
   </PDBx:entryCategory>
   <PDBx:struct_biolCategory>
      <PDBx:struct_biol id="1"></PDBx:struct_biol>
   </PDBx:struct_biolCategory>
   <PDBx:atom_sitesCategory>
      <PDBx:atom_sites entry_id="3HYA">
         <PDBx:fract_transf_matrix11>.086730</PDBx:fract_transf_matrix11>
         <PDBx:fract_transf_matrix12>0.000000</PDBx:fract_transf_matrix12>
         <PDBx:fract_transf_matrix13>0.000000</PDBx:fract_transf_matrix13>
         <PDBx:fract_transf_matrix21>0.000000</PDBx:fract_transf_matrix21>
         <PDBx:fract_transf_matrix22>.101122</PDBx:fract_transf_matrix22>
         <PDBx:fract_transf_matrix23>0.000000</PDBx:fract_transf_matrix23>
         <PDBx:fract_transf_matrix31>0.000000</PDBx:fract_transf_matrix31>
         <PDBx:fract_transf_matrix32>0.000000</PDBx:fract_transf_matrix32>
         <PDBx:fract_transf_matrix33>.029533</PDBx:fract_transf_matrix33>
         <PDBx:fract_transf_vector1>0.00000</PDBx:fract_transf_vector1>
         <PDBx:fract_transf_vector2>0.00000</PDBx:fract_transf_vector2>
         <PDBx:fract_transf_vector3>0.00000</PDBx:fract_transf_vector3>
      </PDBx:atom_sites>
   </PDBx:atom_sitesCategory>
   <PDBx:citationCategory>
      <PDBx:citation id="primary">
         <PDBx:title>Hyaluronic acid: molecular conformations and interactions in two sodium salts.</PDBx:title>
         <PDBx:journal_abbrev>J.Mol.Biol.</PDBx:journal_abbrev>
         <PDBx:journal_volume>95</PDBx:journal_volume>
         <PDBx:page_first>359</PDBx:page_first>
         <PDBx:page_last>384</PDBx:page_last>
         <PDBx:year>1975</PDBx:year>
         <PDBx:journal_id_ASTM>JMOBAK</PDBx:journal_id_ASTM>
         <PDBx:country>UK</PDBx:country>
         <PDBx:journal_id_ISSN>0022-2836</PDBx:journal_id_ISSN>
         <PDBx:journal_id_CSD>0070</PDBx:journal_id_CSD>
         <PDBx:pdbx_database_id_PubMed>1152059</PDBx:pdbx_database_id_PubMed>
      </PDBx:citation>
      <PDBx:citation id="1">
         <PDBx:title>Lals, a Linked-Atom Least-Squares Reciprocal-Space Refinement System Incorporating Stereochemical Restraints to Supplement Sparse Diffraction Data</PDBx:title>
         <PDBx:journal_abbrev>Acta Crystallogr.,Sect.A</PDBx:journal_abbrev>
         <PDBx:journal_volume>34</PDBx:journal_volume>
         <PDBx:page_first>3</PDBx:page_first>
         <PDBx:year>1978</PDBx:year>
         <PDBx:journal_id_ASTM>ACACBN</PDBx:journal_id_ASTM>
         <PDBx:country>DK</PDBx:country>
         <PDBx:journal_id_ISSN>0567-7394</PDBx:journal_id_ISSN>
         <PDBx:journal_id_CSD>0108</PDBx:journal_id_CSD>
      </PDBx:citation>
      <PDBx:citation id="2">
         <PDBx:title>Hyaluronic Acid, Structure of a Fully Extended 3-Fold Helical Sodium Salt and Comparison with the Less Extended 4-Fold Helical Forms</PDBx:title>
         <PDBx:journal_abbrev>J.Mol.Biol.</PDBx:journal_abbrev>
         <PDBx:journal_volume>99</PDBx:journal_volume>
         <PDBx:page_first>219</PDBx:page_first>
         <PDBx:year>1975</PDBx:year>
         <PDBx:journal_id_ASTM>JMOBAK</PDBx:journal_id_ASTM>
         <PDBx:country>UK</PDBx:country>
         <PDBx:journal_id_ISSN>0022-2836</PDBx:journal_id_ISSN>
         <PDBx:journal_id_CSD>0070</PDBx:journal_id_CSD>
      </PDBx:citation>
   </PDBx:citationCategory>
   <PDBx:computingCategory>
      <PDBx:computing entry_id="3HYA">
         <PDBx:structure_refinement>LINKED-ATOM LEAST-SQUARES MODEL-BUILDING PROCEDURE</PDBx:structure_refinement>
      </PDBx:computing>
   </PDBx:computingCategory>
   <PDBx:database_2Category>
      <PDBx:database_2 database_id="PDB" database_code="3HYA"></PDBx:database_2>
      <PDBx:database_2 database_id="NDB" database_code="3HYA"></PDBx:database_2>
      <PDBx:database_2 database_id="RCSB" database_code="3HYA"></PDBx:database_2>
   </PDBx:database_2Category>
   <PDBx:entityCategory>
      <PDBx:entity id="1">
         <PDBx:type>polymer</PDBx:type>
         <PDBx:src_method>man</PDBx:src_method>
         <PDBx:pdbx_description>SUGAR (8-MER)</PDBx:pdbx_description>
         <PDBx:formula_weight>1535.295</PDBx:formula_weight>
         <PDBx:pdbx_number_of_molecules>1.</PDBx:pdbx_number_of_molecules>
      </PDBx:entity>
      <PDBx:entity id="2">
         <PDBx:type>non-polymer</PDBx:type>
         <PDBx:src_method>syn</PDBx:src_method>
         <PDBx:pdbx_description>SODIUM ION</PDBx:pdbx_description>
         <PDBx:formula_weight>22.990</PDBx:formula_weight>
         <PDBx:pdbx_number_of_molecules>4.</PDBx:pdbx_number_of_molecules>
      </PDBx:entity>
      <PDBx:entity id="3">
         <PDBx:type>water</PDBx:type>
         <PDBx:src_method>nat</PDBx:src_method>
         <PDBx:pdbx_description>water</PDBx:pdbx_description>
         <PDBx:formula_weight>18.015</PDBx:formula_weight>
         <PDBx:pdbx_number_of_molecules>8.</PDBx:pdbx_number_of_molecules>
      </PDBx:entity>
   </PDBx:entityCategory>
   <PDBx:entity_poly_seqCategory>
      <PDBx:entity_poly_seq entity_id="1" num="1" mon_id="GCU"></PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" num="2" mon_id="NAG"></PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" num="3" mon_id="GCU"></PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" num="4" mon_id="NAG"></PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" num="5" mon_id="GCU"></PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" num="6" mon_id="NAG"></PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" num="7" mon_id="GCU"></PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" num="8" mon_id="NAG"></PDBx:entity_poly_seq>
   </PDBx:entity_poly_seqCategory>
   <PDBx:entity_polyCategory>
      <PDBx:entity_poly entity_id="1">
         <PDBx:type>polysaccharide(D)</PDBx:type>
         <PDBx:nstd_linkage>no</PDBx:nstd_linkage>
         <PDBx:nstd_monomer>no</PDBx:nstd_monomer>
         <PDBx:pdbx_seq_one_letter_code>(GCU)(NAG)(GCU)(NAG)(GCU)(NAG)(GCU)(NAG)</PDBx:pdbx_seq_one_letter_code>
         <PDBx:pdbx_seq_one_letter_code_can>XXXXXXXX</PDBx:pdbx_seq_one_letter_code_can>
      </PDBx:entity_poly>
   </PDBx:entity_polyCategory>
   <PDBx:pdbx_poly_seq_schemeCategory>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" seq_id="1" mon_id="GCU">
         <PDBx:ndb_seq_num>1</PDBx:ndb_seq_num>
         <PDBx:pdb_seq_num>1</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>1</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>GCU</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>GCU</PDBx:auth_mon_id>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" seq_id="2" mon_id="NAG">
         <PDBx:ndb_seq_num>2</PDBx:ndb_seq_num>
         <PDBx:pdb_seq_num>2</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>2</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>NAG</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>NAG</PDBx:auth_mon_id>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" seq_id="3" mon_id="GCU">
         <PDBx:ndb_seq_num>3</PDBx:ndb_seq_num>
         <PDBx:pdb_seq_num>3</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>3</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>GCU</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>GCU</PDBx:auth_mon_id>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" seq_id="4" mon_id="NAG">
         <PDBx:ndb_seq_num>4</PDBx:ndb_seq_num>
         <PDBx:pdb_seq_num>4</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>4</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>NAG</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>NAG</PDBx:auth_mon_id>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" seq_id="5" mon_id="GCU">
         <PDBx:ndb_seq_num>5</PDBx:ndb_seq_num>
         <PDBx:pdb_seq_num>5</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>5</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>GCU</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>GCU</PDBx:auth_mon_id>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" seq_id="6" mon_id="NAG">
         <PDBx:ndb_seq_num>6</PDBx:ndb_seq_num>
         <PDBx:pdb_seq_num>6</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>6</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>NAG</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>NAG</PDBx:auth_mon_id>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" seq_id="7" mon_id="GCU">
         <PDBx:ndb_seq_num>7</PDBx:ndb_seq_num>
         <PDBx:pdb_seq_num>7</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>7</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>GCU</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>GCU</PDBx:auth_mon_id>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" seq_id="8" mon_id="NAG">
         <PDBx:ndb_seq_num>8</PDBx:ndb_seq_num>
         <PDBx:pdb_seq_num>8</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>8</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>NAG</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>NAG</PDBx:auth_mon_id>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
   </PDBx:pdbx_poly_seq_schemeCategory>
   <PDBx:pdbx_nonpoly_schemeCategory>
      <PDBx:pdbx_nonpoly_scheme asym_id="B" ndb_seq_num="1">
         <PDBx:entity_id>2</PDBx:entity_id>
         <PDBx:mon_id>NA</PDBx:mon_id>
         <PDBx:pdb_seq_num>1</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>1</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>NA</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>NA</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="C" ndb_seq_num="1">
         <PDBx:entity_id>2</PDBx:entity_id>
         <PDBx:mon_id>NA</PDBx:mon_id>
         <PDBx:pdb_seq_num>2</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>2</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>NA</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>NA</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="D" ndb_seq_num="1">
         <PDBx:entity_id>2</PDBx:entity_id>
         <PDBx:mon_id>NA</PDBx:mon_id>
         <PDBx:pdb_seq_num>3</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>3</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>NA</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>NA</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="E" ndb_seq_num="1">
         <PDBx:entity_id>2</PDBx:entity_id>
         <PDBx:mon_id>NA</PDBx:mon_id>
         <PDBx:pdb_seq_num>4</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>4</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>NA</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>NA</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="F" ndb_seq_num="1">
         <PDBx:entity_id>3</PDBx:entity_id>
         <PDBx:mon_id>HOH</PDBx:mon_id>
         <PDBx:pdb_seq_num>5</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>5</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>HOH</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>HOH</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="F" ndb_seq_num="2">
         <PDBx:entity_id>3</PDBx:entity_id>
         <PDBx:mon_id>HOH</PDBx:mon_id>
         <PDBx:pdb_seq_num>6</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>6</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>HOH</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>HOH</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="F" ndb_seq_num="3">
         <PDBx:entity_id>3</PDBx:entity_id>
         <PDBx:mon_id>HOH</PDBx:mon_id>
         <PDBx:pdb_seq_num>7</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>7</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>HOH</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>HOH</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="F" ndb_seq_num="4">
         <PDBx:entity_id>3</PDBx:entity_id>
         <PDBx:mon_id>HOH</PDBx:mon_id>
         <PDBx:pdb_seq_num>8</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>8</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>HOH</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>HOH</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="F" ndb_seq_num="5">
         <PDBx:entity_id>3</PDBx:entity_id>
         <PDBx:mon_id>HOH</PDBx:mon_id>
         <PDBx:pdb_seq_num>9</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>9</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>HOH</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>HOH</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="F" ndb_seq_num="6">
         <PDBx:entity_id>3</PDBx:entity_id>
         <PDBx:mon_id>HOH</PDBx:mon_id>
         <PDBx:pdb_seq_num>10</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>10</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>HOH</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>HOH</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="F" ndb_seq_num="7">
         <PDBx:entity_id>3</PDBx:entity_id>
         <PDBx:mon_id>HOH</PDBx:mon_id>
         <PDBx:pdb_seq_num>11</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>11</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>HOH</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>HOH</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
      <PDBx:pdbx_nonpoly_scheme asym_id="F" ndb_seq_num="8">
         <PDBx:entity_id>3</PDBx:entity_id>
         <PDBx:mon_id>HOH</PDBx:mon_id>
         <PDBx:pdb_seq_num>12</PDBx:pdb_seq_num>
         <PDBx:auth_seq_num>12</PDBx:auth_seq_num>
         <PDBx:pdb_mon_id>HOH</PDBx:pdb_mon_id>
         <PDBx:auth_mon_id>HOH</PDBx:auth_mon_id>
      </PDBx:pdbx_nonpoly_scheme>
   </PDBx:pdbx_nonpoly_schemeCategory>
   <PDBx:refine_histCategory>
      <PDBx:refine_hist cycle_id="LAST">
         <PDBx:pdbx_number_atoms_protein>0</PDBx:pdbx_number_atoms_protein>
         <PDBx:pdbx_number_atoms_nucleic_acid>0</PDBx:pdbx_number_atoms_nucleic_acid>
         <PDBx:pdbx_number_atoms_ligand>172</PDBx:pdbx_number_atoms_ligand>
         <PDBx:d_res_high>3.0</PDBx:d_res_high>
         <PDBx:d_res_low xsi:nil="true" />
      </PDBx:refine_hist>
   </PDBx:refine_histCategory>
   <PDBx:structCategory>
      <PDBx:struct entry_id="3HYA">
         <PDBx:title>HYALURONIC ACID, MOLECULAR CONFORMATIONS AND INTERACTIONS IN TWO SODIUM SALTS</PDBx:title>
         <PDBx:pdbx_descriptor>HYALURONIC ACID (POLY D-GLUCURONIC ACID-N-ACETYL-D-GLUCOSAMINE) SODIUM SALT, ORTHORHOMBIC FORM.</PDBx:pdbx_descriptor>
      </PDBx:struct>
   </PDBx:structCategory>
   <PDBx:struct_asymCategory>
      <PDBx:struct_asym id="A">
         <PDBx:pdbx_blank_PDB_chainid_flag>Y</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
         <PDBx:entity_id>1</PDBx:entity_id>
      </PDBx:struct_asym>
      <PDBx:struct_asym id="B">
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
         <PDBx:entity_id>2</PDBx:entity_id>
      </PDBx:struct_asym>
      <PDBx:struct_asym id="C">
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
         <PDBx:entity_id>2</PDBx:entity_id>
      </PDBx:struct_asym>
      <PDBx:struct_asym id="D">
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
         <PDBx:entity_id>2</PDBx:entity_id>
      </PDBx:struct_asym>
      <PDBx:struct_asym id="E">
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
         <PDBx:entity_id>2</PDBx:entity_id>
      </PDBx:struct_asym>
      <PDBx:struct_asym id="F">
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
         <PDBx:entity_id>3</PDBx:entity_id>
      </PDBx:struct_asym>
   </PDBx:struct_asymCategory>
   <PDBx:struct_biol_genCategory>
      <PDBx:struct_biol_gen biol_id="1" asym_id="A" symmetry="1_555">
         <PDBx:pdbx_full_symmetry_operation>x,y,z</PDBx:pdbx_full_symmetry_operation>
      </PDBx:struct_biol_gen>
      <PDBx:struct_biol_gen biol_id="1" asym_id="B" symmetry="1_555">
         <PDBx:pdbx_full_symmetry_operation>x,y,z</PDBx:pdbx_full_symmetry_operation>
      </PDBx:struct_biol_gen>
      <PDBx:struct_biol_gen biol_id="1" asym_id="C" symmetry="1_555">
         <PDBx:pdbx_full_symmetry_operation>x,y,z</PDBx:pdbx_full_symmetry_operation>
      </PDBx:struct_biol_gen>
      <PDBx:struct_biol_gen biol_id="1" asym_id="D" symmetry="1_555">
         <PDBx:pdbx_full_symmetry_operation>x,y,z</PDBx:pdbx_full_symmetry_operation>
      </PDBx:struct_biol_gen>
      <PDBx:struct_biol_gen biol_id="1" asym_id="E" symmetry="1_555">
         <PDBx:pdbx_full_symmetry_operation>x,y,z</PDBx:pdbx_full_symmetry_operation>
      </PDBx:struct_biol_gen>
      <PDBx:struct_biol_gen biol_id="1" asym_id="F" symmetry="1_555">
         <PDBx:pdbx_full_symmetry_operation>x,y,z</PDBx:pdbx_full_symmetry_operation>
      </PDBx:struct_biol_gen>
   </PDBx:struct_biol_genCategory>
   <PDBx:struct_connCategory>
      <PDBx:struct_conn id="covale1">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_comp_id>GCU</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id xsi:nil="true" />
         <PDBx:ptnr1_label_atom_id>O4</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_comp_id>NAG</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id xsi:nil="true" />
         <PDBx:ptnr2_label_atom_id>C1</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>GCU</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>1</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>NAG</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>2</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale2">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_comp_id>NAG</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id xsi:nil="true" />
         <PDBx:ptnr1_label_atom_id>O3</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_comp_id>GCU</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id xsi:nil="true" />
         <PDBx:ptnr2_label_atom_id>C1</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>NAG</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>2</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>GCU</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>3</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale3">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_comp_id>GCU</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id xsi:nil="true" />
         <PDBx:ptnr1_label_atom_id>O4</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_comp_id>NAG</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id xsi:nil="true" />
         <PDBx:ptnr2_label_atom_id>C1</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>GCU</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>3</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>NAG</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>4</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale4">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_comp_id>NAG</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id xsi:nil="true" />
         <PDBx:ptnr1_label_atom_id>O3</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_comp_id>GCU</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id xsi:nil="true" />
         <PDBx:ptnr2_label_atom_id>C1</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>NAG</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>4</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>GCU</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>5</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale5">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_comp_id>GCU</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id xsi:nil="true" />
         <PDBx:ptnr1_label_atom_id>O4</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_comp_id>NAG</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id xsi:nil="true" />
         <PDBx:ptnr2_label_atom_id>C1</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>GCU</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>5</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>NAG</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>6</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale6">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_comp_id>NAG</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id xsi:nil="true" />
         <PDBx:ptnr1_label_atom_id>O3</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_comp_id>GCU</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id xsi:nil="true" />
         <PDBx:ptnr2_label_atom_id>C1</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>NAG</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>6</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>GCU</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>7</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale7">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_comp_id>GCU</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id xsi:nil="true" />
         <PDBx:ptnr1_label_atom_id>O4</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_comp_id>NAG</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id xsi:nil="true" />
         <PDBx:ptnr2_label_atom_id>C1</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>GCU</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>7</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>NAG</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>8</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
   </PDBx:struct_connCategory>
   <PDBx:softwareCategory>
      <PDBx:software name="LINKED-ATOM" version="LEAST-SQUARES MODEL-BUILDING PROCEDURE">
         <PDBx:classification>refinement</PDBx:classification>
         <PDBx:citation_id xsi:nil="true" />
      </PDBx:software>
   </PDBx:softwareCategory>
   <PDBx:atom_typeCategory>
      <PDBx:atom_type symbol="C"></PDBx:atom_type>
      <PDBx:atom_type symbol="O"></PDBx:atom_type>
      <PDBx:atom_type symbol="H"></PDBx:atom_type>
      <PDBx:atom_type symbol="N"></PDBx:atom_type>
      <PDBx:atom_type symbol="NA"></PDBx:atom_type>
   </PDBx:atom_typeCategory>
   <PDBx:chem_compCategory>
      <PDBx:chem_comp id="GCU">
         <PDBx:type>D-saccharide</PDBx:type>
         <PDBx:name>D-GLUCURONIC ACID</PDBx:name>
         <PDBx:formula>C6 H10 O7</PDBx:formula>
         <PDBx:formula_weight>194.141</PDBx:formula_weight>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="NAG">
         <PDBx:type>D-saccharide</PDBx:type>
         <PDBx:name>N-ACETYL-D-GLUCOSAMINE</PDBx:name>
         <PDBx:pdbx_synonyms>NAG</PDBx:pdbx_synonyms>
         <PDBx:formula>C8 H15 N1 O6</PDBx:formula>
         <PDBx:formula_weight>221.210</PDBx:formula_weight>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="NA">
         <PDBx:type>non-polymer</PDBx:type>
         <PDBx:name>SODIUM ION</PDBx:name>
         <PDBx:formula>NA1 1+</PDBx:formula>
         <PDBx:formula_weight>22.990</PDBx:formula_weight>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="HOH">
         <PDBx:type>non-polymer</PDBx:type>
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